Joint flight with Vostok 3. Acquisition of experimental data on the possibility of establishing a direct link between two space ships; coordination of astronauts' operations; study of the effects of identical spaceflight conditions on the human organism. Popovich had problems with his life support system, resulting in the cabin temperature dropping to 10 degrees Centigrade and the humidity to 35%. The cosmonaut still managed to conduct experiments, including taking colour motion pictures of the terminator between night and day and the cabin interior.

Despite the conditions, Popovich felt able to go for the full four days scheduled. But before the mission, Popovich had been briefed to tell ground control that he was 'observing thunderstorms' if he felt the motion sickness that had plagued Titov and needed to return on the next opportunity. Unfortunately he actually did report seeing thunderstorms over the Gulf of Mexico, and ground control took this as a request for an early return. He was ordered down a day early, landing within a few mintutes of Nikolayev. Only on the ground was it discovered that he was willing to go the full duration, and that ground control had thought he had given the code. Recovered August 15, 1962 6:59 GMT. Landed 48:09 N 71:51 E.

The planned first flight of the Soyuz VI combat spacecraft was planned for early 1969, beating America's equivalent Manned Orbiting Lab. The project was cancelled in 1968.

Planned third and final Russian circumlunar flight. On 24 September 1968 Popovich/Makarov were the prime candidates for the third Soviet circumlunar flight. When the crews were named, Makarov was moved to the first crew and Sevastyanov was named Popovich's flight engineer.

Planned first crew to the first Almaz space station. Cancelled after the loss of control of Almaz OPS 1 (Salyut 2) in orbit.

On 4 July Soyuz 14 docked with the Salyut 3 space station after 15 revolutions of the earth. The planned experimental program included manned military reconnaissance of the earth's surface, assessing the fundamental value of such observations, and some supplemental medico-biological research. All objectives were successfully completed and the spacecraft was recovered on July 19, 1974 at 12:21 GMT, landing within 2 km of the aim point 140 km SE Dzkezkazgan. After the crew's return research continued in the development of the on-board systems and the principles of remote control of such a station.